Synthetic Diamond
Lab-grown diamond (LGD; also called laboratory-grown, laboratory-created, man-made, artisan-created, artificial, synthetic, or cultured diamond) is diamond that is produced in a controlled technological process (in contrast to naturally formed diamond, which is created through geological processes and obtained by mining). Unlike diamond simulants (imitations of diamond made of superficially-similar non-diamond materials), synthetic diamonds are composed of the same material as naturally formed diamonds – pure carbon crystallized in an isotropic 3D form – and share identical chemical and physical properties.
Laboratory-Grown Diamond Timeline:
1. 1950s:
Union Carbide produces the first Chemical Vapor Deposition (CVD) diamonds in
1952. Others produce diamonds using the high pressure, high temperature (HPHT)
method soon after. These diamonds are used for industrial purposes, such as in
telecommunications and laser optics and as abrasives and more.
2. 1970s:
General Electric researchers create the first gem-quality laboratory-grown
diamonds. They are of high enough clarity and large enough size to be used in
jewelry. GIA scientists publish the first scientific study of laboratory-grown
diamonds in 1971.
3. Mid-1980s:
Manufacturers grow commercial quantities of gem-quality laboratory-grown
diamond crystals. These lab-created diamonds are initially mostly small and
yellowish or brownish in color, but their quality improves over the ensuing
decades.
4. 2000s:
Gem-quality diamonds are created using the chemical-vapor deposition (CVD)
method, which requires lower pressures and temperatures than the HPHT method.
5. Mid-2010s:
Colorless laboratory-grown diamonds are available in the jewelry market in
commercial quantities. Both HPHT and CVD continue to be popular methods of
laboratory-grown diamond production.
HPHT and CVD (high-pressure high-temperature and chemical
vapor deposition, respectively ) are the important methods used to produce
synthetic diamond. The two processes still dominate synthetic diamond
production. A third method in which nanometer-sized diamond grains are created
in a detonation of carbon-containing explosives, known as detonation synthesis,
entered the market in the late 1990s. A fourth method, treating graphite with
high-power ultrasound, has been demonstrated in the laboratory, but currently
has no commercial application.
The properties of man-made diamond depend on the
manufacturing process. Some synthetic diamonds have properties such as hardness,
thermal conductivity and electron mobility that are superior to those of most
naturally formed diamonds. Synthetic diamond is widely used in abrasives, in
cutting and polishing tools and in heat sinks. Electronic applications of
synthetic diamond are being developed, including high-power switches at power
stations, high-frequency field-effect transistors and light-emitting diodes.
Synthetic diamond detectors of ultraviolet (UV) light or high-energy particles
are used at high-energy research facilities and are available commercially. Due
to its unique combination of thermal and chemical stability, low thermal expansion
and high optical transparency in a wide spectral range, synthetic diamond is
becoming the most popular material for optical windows in high-power CO2 lasers and gyrotrons.
It is estimated that 98% of industrial-grade diamond demand is supplied with
synthetic diamonds.
Both CVD and HPHT diamonds can be cut into gems and various
colors can be produced: clear white, yellow, brown, blue, green and orange. The
advent of synthetic gems on the market created major concerns in the diamond
trading business, as a result of which special spectroscopic devices and
techniques have been developed to distinguish synthetic and natural diamonds.
Natural
diamonds are classified according to their optical properties, with most being
Type I and having an absorption edge of around 330 nm, and a small group being
Type II with an absorption edge of about 220 nm.
https://en.wikipedia.org/wiki/Synthetic_diamond
https://www.britannica.com/science/synthetic-diamond
https://4cs.gia.edu/en-us/laboratory-grown-diamond/
https://www.capetowndiamondmuseum.org/blog/2018/06/real-diamonds-vs-synthetic-diamonds/
https://cen.acs.org/articles/82/i5/FACETS-MAN-MADE-DIAMONDS.html
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